Dirhodium(II)-Catalyzed Sulfide Oxygenations: Catalyst Removal by Coprecipitation with Sulfoxides
Lili Zhao, Hongyang Zhang and Yuanhua Wang*
*College of Chemistry, Sichuan University, Chengdu, 610064,
P. R. China, Email: yhwang
scu.edu.cn
L. Zhao, H. Zhang, Y. Wang, J. Org. Chem., 2016, 81, 129-134.
DOI: 10.1021/acs.joc.5b02400
see article for more reactions
Abstract
The dirhodium(II) carboxylate complex Rh2(esp)2 catalyzes the sulfoxidation of organic sulfides in the presence of tert-butyl hydroperoxide as the oxidant. As the rhodium catalyst is able to precipitate as a Rh2(esp)2-sulfoxide complex following the reaction, its separation and reuse is very convenient without considerable loss of activity.
see article for more examples
While ads financed 62% of the published abstracts in 2024, donations allowed us to publish additional 12%. 26% of the abstracts have been published voluntarly. If you kindly donate, we can publish more freely accessible information and help the chemical community even more:
If you don't like pawalls or a flood of more and more advertising, then you can send a clear signal here!
Key Words
ID: J42-Y2016
