Iron/ABNO-Catalyzed Aerobic Oxidation of Alcohols to Aldehydes and Ketones under Ambient Atmosphere
Lianyue Wang*, SenSen Shang, Guosong Li, Lanhui Ren, Ying Lv and Shuang Gao*
*Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian National Laboratory for Clean Energy, Dalian 116023, China, Email: lianyuewangdicp.ac.cn, sgaodicp.ac.cn
L. Wang, S. Shang, G. Li, L. Ren, Y. Lv, S. Gao, J. Org. Chem., 2016, 81, 2189-2193.
DOI: 10.1021/acs.joc.6b00009
Abstract
The combination of Fe(NO3)3·9H2O and 9-azabicyclo[3.3.1]nonan-N-oxyl enables an efficient aerobic oxidation of a broad range of primary and secondary alcohols to the corresponding aldehydes and ketones at room temperature with ambient air as the oxidant.
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Key Words
aldehydes, ketones, ABNO, oxygen
ID: J42-Y2016