Nickel-Catalyzed Phosphorylation of Phenol Derivatives via C-O/P-H Cross-Coupling
Jia Yang, Jing Xiao, Tieqiao Chen* and Li-Biao Han*
*College of Chemistry and Chemical Engineering, Hunan
University, Changsha 410082, China; AIST, Tsukuba, Ibaraki 305-8565, Japan,
Email: chentieqiao
hnu.edu.cn, libiao-hanaist.go.jp
J. Yang, J. Xiao, T. Chen, L.-B. Han, J. Org. Chem., 2016, 81, 3911-3916.
DOI: 10.1021/acs.joc.6b00289
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Abstract
In an efficient nickel-catalyzed phosphorylation, various phenyl pivalates coupled readily with hydrogen phosphoryl compounds to afford the corresponding aryl phosphonates and aryl phosphine oxides in very good yields.
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plausible mechanism
Key Words
ID: J42-Y2016
