Manganese-Catalyzed Borylation of Unactivated Alkyl Chlorides
Thomas C. Atack and Silas P. Cook*
*Department of Chemistry, Indiana University, 800 East
Kirkwood Avenue, Bloomington, Indiana 47405-7102, United States, Email: sicook
indiana.edu
T. C. Atack, S. P. Cook, J. Am. Chem. Soc., 2016, 138, 6139-6142.
DOI: 10.1021/jacs.6b03157
Abstract
Very low amounts of Manganese(II) bromide and tetramethylethylenediamine (TMEDA) catalyze the cross coupling of (bis)pinacolatodiboron with a wide range of alkyl halides. This method allows access to primary, secondary, and tertiary boronic esters.
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Iron-Catalyzed Borylation of Alkyl Electrophiles
T. C. Atack, R. M. Lecker, S. P. Cook, J. Am. Chem. Soc., 2014, 136, 9521-9523.
Key Words
ID: J48-Y2016
