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Phosphine-Free, Heterogeneous Palladium-Catalyzed Atom-Efficient Carbonylative Cross-Coupling of Triarylbismuths with Aryl Iodides: Synthesis of Biaryl Ketones

Wenyan Hao, Haiyi Liu, Lin Yin and Mingzhong Cai*

*Ministry of Education and College of Chemistry & Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P. R. of China, Email: mzcaijxnu.edu.cn

W. Hao, H. Liu, L. Yin, M. Cai, J. Org. Chem., 2016, 81, 4244-4251.

DOI: 10.1021/acs.joc.6b00570


Abstract

A highly efficient heterogeneous palladium-catalyzed carbonylative cross-coupling of aryl iodides with triarylbismuths proceeds smoothly at atmospheric CO pressure and provides various valuable biaryl ketones with high atom economy, good to excellent yield, and recyclability of the catalyst.

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Key Words

aryl ketones


ID: J42-Y2016