Organic Chemistry Portal

Abstracts

Search:

Organocatalytic Redox Isomerization of Electron-Deficient Allylic Alcohols: Synthesis of 1,4-Ketoaldehydes

Keshab Mondal, Buddhadeb Mondal and Subhas Chandra Pan*

*Department of Chemistry, Indian Institute of Technology Guwahati, North Guwahati, Assam 781039, India, Email: spaniitg.ernet.in

K. Mondal, B. Mondal, S. C. Pan, J. Org. Chem., 2016, 81, 4835-4840.

DOI: 10.1021/acs.joc.6b00243 (free Supporting Information)


see article for more reactions

Abstract

DABCO is a suitable catalyst for the isomerization of γ-hydroxy enones in an organocatalytic redox isomerization strategy for the synthesis of 1,4-ketoaldehydes in high yields.

see article for more examples



Key Words

isomerization, organocatalysis


ID: J42-Y2016