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Rhodium-Catalyzed ipso-Borylation of Alkylthioarenes via C-S Bond Cleavage

Yuta Uetake, Takashi Niwa and Takamitsu Hosoya*

*Chemical Biology Team, Division of Bio-Function Dynamic Imaging, RIKEN Center for Life Science Technologies, 6-7-3 Minatojima-minamimachi, Chuo-ku, Kobe 650-0047, Japan, Email: takamitsu.hosoyariken.jp

Y. Uetake, T. Niwa, T. Hosoya, Org. Lett., 2016, 18, 2750-2753.

DOI: 10.1021/acs.orglett.6b01250 (free Supporting Information)


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Abstract

Rhodium-catalyzed transformation of alkyl aryl sulfides into arylboronic acid pinacol esters via C-S bond cleavage allows the synthesis of a diverse range of multisubstituted arenes.

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Key Words

borylation


ID: J54-Y2016