Rhodium-Catalyzed ipso-Borylation of Alkylthioarenes via C-S Bond Cleavage
Yuta Uetake, Takashi Niwa and Takamitsu Hosoya*
*Chemical Biology Team, Division of Bio-Function Dynamic
Imaging, RIKEN Center for Life Science Technologies, 6-7-3
Minatojima-minamimachi, Chuo-ku, Kobe 650-0047, Japan, Email: takamitsu.hosoya
riken.jp
Y. Uetake, T. Niwa, T. Hosoya, Org. Lett., 2016, 18, 2750-2753.
DOI: 10.1021/acs.orglett.6b01250
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Abstract
Rhodium-catalyzed transformation of alkyl aryl sulfides into arylboronic acid pinacol esters via C-S bond cleavage allows the synthesis of a diverse range of multisubstituted arenes.
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Key Words
ID: J54-Y2016
