Generation of Hydrogen from Water: A Pd-Catalyzed Reduction of Water Using Diboron Reagent at Ambient Conditions
Devi Prasan Ojha, Karthik Gadde and Kandikere Ramaiah Prabhu*
*Department of Organic Chemistry, Indian Institute of Science, Bangalore 560012, Karnataka, India, Email: prabhuorgchem.iisc.ernet.in
D. P. Ojha, K. Gadde, K. R. Prabhu, Org. Lett., 2016, 18, 5062-5065.
DOI: 10.1021/acs.orglett.6b02508 (free Supporting Information)
see article for more reactions
A Pd-catalyzed reaction of water with a diboron compound as the reductant produces clean hydrogen gas under ambient reaction conditions. The B2Pin2-H2O system enables a selective hydrogenation of olefins in the presence of a palladium catalyst.
see article for more examples