Metal-Free Aromatic Carbon-Phosphorus Bond Formation via a Sandmeyer-Type Reaction
Shuai Wang, Di Qiu, Fanyang Mo, Yan Zhang and Jianbo Wang*
*Beijing National Laboratory of Molecular Sciences (BNLMS), College of Chemistry, Peking University, Beijing 100871, China, Email: wangjbpku.edu.cn
S. Wang, D. Qiu, F. Mo, Y. Zhang, J. Wang, J. Org. Chem., 2016, 81, 11603-11611.
DOI: 10.1021/acs.joc.6b01820 (free Supporting Information)
see article for more reactions
An efficient metal-free phosphorylation process based on a Sandmeyer-type transformation of arylamines proceeds smoothly at room temperature without the exclusion of moisture or air. This reaction tolerates a wide range of functional groups and affords the phosphorylation products in good yields.
see article for more examples