Selective Oxidation of Styrene Derivatives to Ketones over Palladium(0)/Carbon with Hydrogen Peroxide as the Sole Oxidant
Xiaomeng Xia, Xi Gao, Junhui Xu, Chuanfeng Hu, Xinhua Peng*
*School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094, P. R. of China, Email: xhpengmail.njust.edu.cn
X. Xia, X. Gao, J. Xu, C. Hu, X. Peng, Synlett, 2017, 28, 607-610.
DOI: 10.1055/s-0036-1588656 (free Supporting Information)
see article for more reactions
Pd0/C exhibited excellent catalytic activity in the oxidation of styrene derivatives to corresponding ketones with hydrogen peroxide as oxidant. This modified Wacker oxidation is cost-efficient and environmentally friendly and avoids the use of a copper salt as a co-catalyst.
see article for more examples