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Visible-Light-Promoted C-H Arylation by Merging Palladium Catalysis with Organic Photoredox Catalysis

Jian Jiang, Wen-Man Zhang, Jian-Jun Dai , Jun Xu and Hua-Jian Xu*

*School of Biological and Medical Engineering, Hefei University of Technology, Hefei 230009, China, Email: hjxuhfut.edu.cn

J. Jiang, W.-M. Zhang, J.-J. Dai, J. Xu, H.-J. Xu, J. Org. Chem., 2017, 82, 3622-3630.

DOI: 10.1021/acs.joc.7b00140 (free Supporting Information)


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Abstract

The use of a dual palladium/organic photoredox catalytic system enables the directed arylation of arenes with aryldiazonium salts under mild reaction conditions. This reaction serves as not only an alternative route for a broad range of biaryl motifs but also a new example for the application of an organic photoredox catalyst.

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Key Words

biaryls


ID: J42-Y2017