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Iodine-Catalyzed Facile Approach to Sulfones Employing TosMIC as a Sulfonylating Agent

Lingaswamy Kadari, Radha Krishna Palakodety* and Lakshmi Prapurna Yallapragada*

*D-207, Discovery Laboratory, Organic and Biomolecular Chemistry Division, CSIR-Indian Institute of Chemical Technology, Hyderabad 500007, India, Email: prkgeniusiict.res.in, ylprapurna.iictgov.in

L. Kadari, R. K. Palakodety, L. P. Yallapragada, Org. Lett., 2017, 19, 2580-2583.

DOI: 10.1021/acs.orglett.7b00896 (free Supporting Information)


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Abstract

An iodine-catalyzed functionalization of various olefins and alkynes and direct decarboxylative functionalization of cinnamic and propiolic acids with TosMIC provides highy valuable vinyl, allyl, and β-iodo vinylsulfones. This simple, efficient, and environmentally benign approach is attractive to both synthetic and medicinal chemistry.


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Key Words

vinyl sulfones, allyl sulfones


ID: J54-Y2017