Dual Role of H2O2 in Palladium-Catalyzed Dioxygenation of Terminal Alkenes
Jiuzhong Huang, Jianxiao Li, Jia Zheng, Wanqing Wu*, Weigao Hu, Lu Ouyang and Huanfeng Jiang*
*School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, P. R. China, Email: cewuwqscut.edu.cn, jianghfscut.edu.cn
J. Huang, J. Li, J. Zheng, W. Wu, W. Hu, L. Ouyang, H. Jiang, Org. Lett., 2017, 19, 3354-3357.
DOI: 10.1021/acs.orglett.7b01228 (free Supporting Information)
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A palladium-catalyzed, environmentally friendly dioxygenation reaction of simple alkenes enables a rapid assembly of valuable α-hydroxy ketones with high atom economy.
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