Hydroboration of Alkynes Catalyzed by Pyrrolide-Based PNP Pincer-Iron Complexes
Kazunari Nakajima, Takeru Kato and Yoshiaki Nishibayashi*
*Department of Systems Innovation, School of Engineering, The
University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Email: ynishiba
sys.t.u-tokyo.ac.jp
K. Nakajima, T. Kato, Y. Nishibayashi, Org. Lett., 2017, 19, 4323-4326.
DOI: 10.1021/acs.orglett.7b01995
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Abstract
An iron complex bearing a pyrrolide-based PNP pincer ligand enables a catalyzed hydroboration of alkynes with pinacolborane, where the corresponding E-isomers are obtained selectively.
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Key Words
ID: J54-Y2017
