Synthesis of Cyclic Imides by Acceptorless Dehydrogenative Coupling of Diols and Amines Catalyzed by a Manganese Pincer Complex
Noel Angel Espinosa-Jalapa, Amit Kumar, Gregory Leitus, Yael Diskin-Posner and David Milstein*
*Department of Organic Chemistry, The Weizmann Institute of
Science, Rehovot, 76100, Israel, Email: david.milstein
weizmann.ac.il
N. Angel Espinosa-Jalapa, A. Kumar, G. Leitus, Y. Diskin-Posner, D. Milstein, J. Am. Chem. Soc., 2017, 139, 11722-11725.
DOI: 10.1021/jacs.7b08341
Abstract
A manganese pincer complex catalyzes a dehydrogenative coupling of diols and amines to form cyclic imides. The reaction forms hydrogen gas as the sole byproduct, making the overall process atom economical and environmentally benign.
see article for more examples
proposed catalytic cycle
Key Words
ID: J48-Y2017
