Selective Oxidation of Secondary Amines to N,N-Disubstituted Hydroxylamines by Choline Peroxydisulfate
Alireza Banan, Hassan Valizadeh, Akbar Heydari*, Abolghasem Moghimi
*Department of Chemistry, Faculty of Sciences, Azerbajan
Shahid Madani University, 53714-161 Tabriz, Iran,
Email: heydar_a
modares.ac.ir
A. Banan, H. Valizadeh, A. Heydari, A. Moghimi, Synlett, 2017, 28, 2315-2319.
DOI: 10.1055/s-0036-1589089
Abstract
Choline peroxydisulfate - an oxidizing task-specific ionic liquid - enables the preparation of N,N-disubstituted hydroxylamines from secondary amines. This method offers operational simplicity, high selectivity, and green reaction conditions.
see article for more examples
preparation of choline peroxydisulfate
Key Words
hydroxylamines, ionic liquids, choline peroxydisulfate, oxidation, amines, green chemistry
ID: J60-Y2017
