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Choline Peroxydisulfate: Environmentally Friendly Biodegradable Oxidizing TSIL for Selective and Rapid Oxidation of Alcohols

Balu L. Gadilohar, Haribhau S. Kumbhar and Ganapati S. Shankarling*

*Department of Dyestuff Technology, Institute of Chemical Technology, N. P. Marg, Matunga, Mumbai 400 019, India, Email: gs.shankarlingictmumbai.edu.in

B. L. Gadilohar, H. S. Kumbhar, G. S. Shankarling, Ind. Eng. Chem. Res., 2014, 53, 19010-19018.

DOI: 10.1021/ie5032919 (free Supporting Information)


Abstract

The choline- and peroxydisulfate-based environmentally benign biodegradable oxidizing task-specific ionic liquid (TSIL) choline peroxydisulfate (ChPS) was synthesized and characterized. This reagent enables a selective oxidation of alcohols to aldehydes/ketones in very good yields and short reaction time under solvent-free mild reaction conditions without overoxidation to acid.

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preparation of choline peroxydisulfate



Key Words

aldehydes, ketones, ionic liquids, choline peroxydisulfate, oxidation, green chemistry


ID: JXX-Y2014