Choline Peroxydisulfate: Environmentally Friendly Biodegradable Oxidizing TSIL for Selective and Rapid Oxidation of Alcohols
Balu L. Gadilohar, Haribhau S. Kumbhar and Ganapati S. Shankarling*
*Department of Dyestuff Technology, Institute of Chemical
Technology, N. P. Marg, Matunga, Mumbai 400 019, India,
Email: gs.shankarling
ictmumbai.edu.in
B. L. Gadilohar, H. S. Kumbhar, G. S. Shankarling, Ind. Eng. Chem. Res., 2014, 53, 19010-19018.
DOI: 10.1021/ie5032919
Abstract
The choline- and peroxydisulfate-based environmentally benign biodegradable oxidizing task-specific ionic liquid (TSIL) choline peroxydisulfate (ChPS) was synthesized and characterized. This reagent enables a selective oxidation of alcohols to aldehydes/ketones in very good yields and short reaction time under solvent-free mild reaction conditions without overoxidation to acid.
see article for more examples
preparation of choline peroxydisulfate
Key Words
aldehydes, ketones, ionic liquids, choline peroxydisulfate, oxidation, green chemistry
ID: JXX-Y2014
