Hypervalent Iodine Mediated Chemoselective Iodination of Alkynes
Yan Liu*, Daya Huang, Ju Huang and Keiji Maruoka*
*Guangdong University of Technology, No.100, West Waihuan
Road, HEMC, Panyu District, Guangzhou 510006, China; Kyoto University, Sakyo,
Kyoto 606-8502, Japan, Email: yanliu
gdut.edu.cn, maruokakuchem.kyoto-u.ac.jp
Y. Liu, D. Huang, J. Huang, K. Maruoka, J. Org. Chem., 2017, 82, 11865-11871.
DOI: 10.1021/acs.joc.7b01555
Abstract
Hypervalent iodine reagents mediate practical oxidative iodinations for the chemoselective mono-, di-, and tri-iodination of alkynes. The reaction conditions were systematically optimized by altering the iodine source and/or the hypervalent iodine reagent system.
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Key Words
iodoalkynes, iodoalkenes, PIDA
ID: J42-Y2017
