Bimetallic Cobalt-Rhodium Nanoparticle-Catalyzed Reductive Amination of Aldehydes with Nitroarenes Under Atmospheric Hydrogen
Isaac Choi, Supill Chun and Young Keun Chung*
*Department of Chemistry, College of Natural Sciences, Seoul
National University, Seoul 08826, Korea, Email: ykchung
snu.ac.kr
I. Choi, S. Chun, Y. K. Chung, J. Org. Chem., 2017, 82, 12771-12777.
DOI: 10.1021/acs.joc.7b02019
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Abstract
Cobalt-rhodium heterobimetallic nanoparticles catalyze a tandem reductive amination of aldehydes with nitroaromatics without any additives under mild conditions (1 atm H2 and 25 °C). This procedure can be scaled up to the gram scale, and the catalyst can be reused more than six times without loss of activity.
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Key Words
ID: J42-Y2017
