Palladium-Catalyzed Oxidative Borylation of Allylic C-H Bonds in Alkenes
Lujia Mao, Rüdiger Bertermann, Simon G. Rachor, Kálmán J. Szabó* and Todd B. Marder*
*Stockholm University, SE-10691 Stockholm, Sweden; Julius-Maximilians-Universität
Würzburg, 97074 Würzburg, Germany, Email: kalman
organ.su.se,
todd.marderuni-wuerzburg.de
L. Mao, R. Bertermann, K. Emmert, K. J. Szabo, T. B. Marder, Org. Lett., 2017, 19, 6586-6589.
DOI: 10.1021/acs.orglett.7b03296
see article for more reactions
Abstract
A palladium pincer complex catalyzes an allylic C-H borylation of alkenes in high yields. The transformation exhibits high regio- and stereoselectivity with various linear alkenes. Preliminary mechanistic studies indicate that this C-H borylation reaction proceeds via Pd(IV) pincer complex intermediates.
see article for more examples
proposed mechanism
Key Words
ID: J54-Y2017
