An Additive-Free, Base-Catalyzed Protodesilylation of Organosilanes
Wubing Yao, Rongrong Li, Huajiang Jiang and Deman Han*
*Department of Chemistry, Taizhou University, Jiaojiang 318000, China, Email: hdmtzc126.com
W. Yao, R. Li, H. Jiang, D. Han, J. Org. Chem., 2018, 83, 2250-2255.
see article for more reactions
Low loadings of KOTMS catalyze an additive-free, C-, N-, O-, and S-Si bond cleavage of various organosilanes under mild conditions. The novel catalyst system exhibits high efficiency and good functional group compatibility, providing the corresponding products in good to excellent yields.
see article for more examples