Pd^II-Porphyrin Complexes - the First Use as Safer and Efficient Catalysts for Miyaura Borylation

Kanusu Umamaheswara Rao, Katta Venkateswarlu*

*Laboratory for Synthetic & Natural Products Chemistry, Department of Chemistry, Yogi Vemana University, Kadapa 516 003, India, Email: kvenkatyogivemanauniversity.ac.in

K. U. Rao, K. Ventateswarlu, Synlett, 2018, 29, 1055-1060.

DOI: 10.1055/s-0036-1591549

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Abstract

The use of a Pd^II-porphyrin complex as a catalyst enables a simple and convenient synthesis of pinacol arylboronates from aryl/heteroaryl bromides and bis(pinacolato)diborane.

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Key Words

Miyaura borylation, Pd^II-porphyrin complex, pinacol arylboronates

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ID: J60-Y2018