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Enantioselective Pd(II)-Catalyzed Intramolecular Oxidative 6-endo Aminoacetoxylation of Unactivated Alkenes

Xiaoxu Qi, Chaohuang Chen, Chuanqi Hou, Liang Fu, Pinhong Chen and Guosheng Liu*

*Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, People's Republic of China, Email: gliusioc.ac.cn

X. Qi, C. Chen, C. Hou, L. Fu, P. Chen, G. Liu, J. Am. Chem. Soc., 2018, 140, 7415-7419.

DOI: 10.1021/jacs.8b03767


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Abstract

A Pd-catalyzed, asymmetric 6-endo aminoacetoxylation of unactivated alkenes provides chiral β-acetoxylated piperidines with excellent chemo-, regio- and enantioselectivities under very mild reaction conditions using a designed pyridine-oxazoline (Pyox) ligand.

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Key Words

piperidines, PIDA


ID: J48-Y2018