Au Nanoparticle-Catalyzed Insertion of Carbenes from α-Diazocarbonyl Compounds into Hydrosilanes

Marios Kidonakis and Manolis Stratakis*

*Department of Chemistry, University of Crete, Voutes 71003, Heraklion, Greece, Email: stratakisuoc.gr

M. Kidonakis, M. Stratakis, Org. Lett., 2018, 20, 4086-4089.

DOI: 10.1021/acs.orglett.8b01638

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Abstract

Supported Au nanoparticles on TiO₂ catalyze the insertion of carbenes from α-diazocabonyl compounds into hydrosilanes without ligands or additives. This purely heterogeneous process allows the recycling and reuse of the catalyst.

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Key Words

silanes

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ID: J54-Y2018