Visible-Light-Enabled Construction of Thiocarbamates from Isocyanides, Thiols, and Water at Room Temperature
Wei Wei*, Pengli Bao, Huilan Yue*, Sitong Liu, Leilei Wang, Yudong Li, Daoshan Yang
*Qingdao University of Science and Technology, Qingdao 266042; Qinghai Provincial Key Laboratory of Tibetan Medicine Research, Qinghai 810008, China, P. R. China, Email: weiweiqfnu163.com, hlyuenwipb.cas.cn
W. Wei, P. Bao, H. Yue, S. Liu, L. Wang, Y. Li, D. Yang, Org. Lett., 2018, 20, 5291-5295.
see article for more reactions
A convenient visible-light-induced reaction of isocyanides, thiols, and water under mild reaction conditions provides various thiocarbamates in good yields in the presence of cheap Rose Bengal as the photocatalyst.
see article for more examples
thiocarbamates, air, photochemistry