Synthesis of Thiophosphates by Coupling of Phosphates with Bunte Salts under Mild Conditions
Cong Min, Rongxing Zhang, Qian Liu, Sen Lin*, Zhaohua Yan*
*College of Chemistry, Nanchang University, Nanchang, Jiangxi 330031, P. R. of China, Email:
senlin
ncu.edu.cn, yanzhncu.edu.cn
C. Min, R. Zhang, Q. Liu, S. Lin, Z. Yan, Synthesis, 2018, 50, 2027-2030.
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Abstract
A NaBr-catalyzed coupling reaction of Bunte salts with phosphonates enables a simple, green, and efficient synthesis of of thiophosphates in good yields in the presence of an acid and hydrogen peroxide (30%).
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Key Words
hydrogen peroxide, thiophosphates, Bunte salts, acids
ID: J66-Y2018
