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Synthesis of Thiophosphates by Coupling of Phosphates with Bunte Salts under Mild Conditions

Cong Min, Rongxing Zhang, Qian Liu, Sen Lin*, Zhaohua Yan*

*College of Chemistry, Nanchang University, Nanchang, Jiangxi 330031, P. R. of China, Email:,

C. Min, R. Zhang, Q. Liu, S. Lin, Z. Yan, Synthesis, 2018, 50, 2027-2030.

DOI: 10.1055/s-0037-1609556

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A NaBr-catalyzed coupling reaction of Bunte salts with phosphonates enables a simple, green, and efficient synthesis of of thiophosphates in good yields in the presence of an acid and hydrogen peroxide (30%).

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Key Words

hydrogen peroxide, thiophosphates, Bunte salts, acids

ID: J66-Y2018