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Highly β(Z)-Selective Hydrosilylation of Terminal Alkynes Catalyzed by Thiolate-Bridged Dirhodium Complexes

Xiangyu Zhao, Dawei Yang*, Yahui Zhang, Baomin Wang, Jingping Qu

*State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, People's Republic of China, Email: yangdwdlut.edu.cn

X. Zhao, D. Yang, Y. Zhang, B. Wang, J. Qu, Org. Lett., 2018, 20, 5357-5361.

DOI: 10.1021/acs.orglett.8b02267 (free Supporting Information)


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Abstract

Monothiolate-bridged dirhodium complexes can smoothly facilitate highly regioselective and stereoselective hydrosilylation of terminal alkynes to afford β(Z) vinylsilanes with good functional group compatibility.

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Key Words

vinylsilanes


ID: J54-Y2018