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Transition-Metal-Free Arylations of In-Situ Generated Sulfenates with Diaryliodonium Salts

Hao Yu, Zhen Li, Carsten Bolm*

*Institute of Organic Chemistry, RWTH Aachen University Landoltweg 1, 52074 Aachen, Germany, Email: carsten.bolmoc.rwth-aachen

H. Yu, Z. Li, C. Bolm, Org. Lett., 2018, 20, 7104-7106.

DOI: 10.1021/acs.orglett.8b03046

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A mild transition-metal-free arylation of sulfenate anions generated from β-sulfinyl esters with diaryliodonium salts provides a wide range of S,S-diaryl and S-alkyl S-aryl sulfoxides.

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Key Words

aryl sulfones

ID: J54-Y2018