Electrochemical Dehydrogenative Phosphorylation of Alcohols for the Synthesis of Organophosphinates
Lingling Deng, Yang Wang, Haibo Mei, Yi Pan, Jianlin Han*
*Jiangsu Key Laboratory of Advanced Organic Materials, Nanjing University, Nanjing 210093, China,
Email: hanjl
njfu.edu.cn
L. Deng, Y. Wang, H. Mei, Y. Pan, J. Han, J. Org. Chem., 2019, 84, 949-956.
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Abstract
An electrochemical cross-dehydrogenative-coupling reaction between alcohols and secondary phosphine oxides provides organophosphinates in an eco-friendly and efficient manner at room temperature without the addition of any oxidant, metal catalyst, or additive.
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proposed mechanism
Key Words
organophosphinates, electrochemistry
ID: J42-Y2019
