Dehydrative Allylation of Amine with Allyl Alcohol by Titanium Oxide Supported Molybdenum Oxide Catalyst

Yoshihiro Kon*, Takuya Nakashima, Tadahiro Fujitani, Toru Murayama, Wataru Ueda*

*National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565; Kanagawa University, 3-27, Rokkakubashi, Kanagawa-ku, Yokohama 221-8686, Japan, Email: y-konaist.go.jp, uedawkanagawa-u.ac.jp

Y. Kon, T. Nakashima, T. Fujitani, T. Murayama, W. Ueda, Synlett, 2019, 30, 287-292.

DOI: 10.1055/s-0037-1612010

---

see article for more reactions

Abstract

A dehydrative allylation of allyl alcohol with amines provides various allyl amines in the presence of MoO₃/TiO₂ as solid catalyst. The catalyst can be reused three times without loss of activity.

see article for more examples

---

---

Key Words

allyl amines, molybdenum oxide catalyst, allyl alcohols, titanium oxide, dehydrative allylation

---

ID: J72-Y2019