Dehydrative Allylation of Amine with Allyl Alcohol by Titanium Oxide Supported Molybdenum Oxide Catalyst
Yoshihiro Kon*, Takuya Nakashima, Tadahiro Fujitani, Toru Murayama, Wataru Ueda*
*National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565; Kanagawa University, 3-27, Rokkakubashi, Kanagawa-ku, Yokohama 221-8686, Japan, Email: y-konaist.go.jp, uedawkanagawa-u.ac.jp
Y. Kon, T. Nakashima, T. Fujitani, T. Murayama, W. Ueda, Synlett, 2019, 30, 287-292.
DOI: 10.1055/s-0037-1612010 (free Supporting Information)
see article for more reactions
A dehydrative allylation of allyl alcohol with amines provides various allyl amines in the presence of MoO3/TiO2 as solid catalyst. The catalyst can be reused three times without loss of activity.
see article for more examples
allyl amines, molybdenum oxide catalyst, allyl alcohols, titanium oxide, dehydrative allylation