Controllable Intramolecular Unactivated C(sp³)-H Amination and Oxygenation of Carbamates

Qihang Guo, Xiang Ren, Zhan Lu*

*Department of Chemistry, Zhejiang University, 866 Yuhangtang Road, Hangzhou 310058, China, Email: luzhanzju.edu.cn

Q. Guo, X. Ren, Z. Lu, Org. Lett., 2019, 21, 880-884.

DOI: 10.1021/acs.orglett.8b03299

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Abstract

The combination of visible-light photocatalysis and earth-abundant transition metal catalysis enables an intramolecular C(sp3)-H amination and oxygenation of unactivated carbamates to provide useful amino alcohol and diol derivatives from readily available tertiary alcohol derivatives.

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Key Words

oxazolidinones, photochemistry

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ID: J54-Y2019