Cycloaddition of Aziridine with CO₂/CS₂ Catalyzed by Amidato Divalent Lanthanide Complexes

Yueqin Xie, Chengrong Lu, Bei Zhao*, Qianyu Wang, Yingming Yao

*College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, People’s Republic of China, Email: zhaobeisuda.edu.cn

Y. Xie, C. Lu, B. Zhao, Q. Wang, Y. Yao, J. Org. Chem., 2019, 84, 1951-1958.

DOI: 10.1021/acs.joc.8b02924

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Abstract

Amidato lanthanide amides were applied in the cycloaddition reactions of aziridines with carbon dioxide (CO₂) or carbon disulfide (CS₂) under mild conditions to provide the corresponding oxazolidinones and thiazolidine-2-thiones in good yields with good functional group tolerance.

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Key Words

oxazolidinones, 1,3-thiazolidine-2-thiones

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ID: J42-Y2019