N-Arylation of NH-Sulfoximines via Dual Nickel Photocatalysis
Alexander Wimmer, Burkhard König*
*Department of Chemistry and Pharmacy, Institute of Organic Chemistry, University of Regensburg, Universitätsstraße 31, 93051 Regensburg, Germany,
Email: burkhard.koenig
chemie.uni-regensburg.de
A. Wimmer, B. König, Org. Lett., 2019, 21, 2740-2744.
DOI: 10.1021/acs.orglett.9b00698
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Abstract
A dual nickel photocatalytic approach enables a scalable synthesis of a broad scope of N-arylated sulfoximines from the respective free NH-sulfoximines and bromoarenes. The reaction exhibits a high functional group tolerance. In addition, other sulfoximidoyl derivatives like sulfonimidamides and sulfinamides can smoothly be converted under the reaction conditions.
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Key Words
sulfoximines, photochemistry
ID: J54-Y2019
