Nickel-Catalyzed Decarboxylative Alkenylation of Anhydrides with Vinyl Triflates or Halides
Hui Chen, Shuhao Sun, Xuebin Liao*
*School of Pharmaceutical Sciences, Beijing Advanced Innovation Center for Structural Biology, Tsinghua
University, Beijing 100084, China, Email: liaoxuebin
mail.tsinghua.edu.cn
H. Chen, S. Sun, X. Liao, Org. Lett., 2019, 21, 3625-3630.
DOI: 10.1021/acs.orglett.9b01048
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Abstract
Nickel catalysis accomplishes a decarboxylative cross-coupling of aliphatic acid anhydrides with vinyl triflates or halides. This methodology works well with a broad array of substrates and features abundant functional group tolerance.
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Key Words
alkenylation, cyclohexenes, zinc
ID: J54-Y2019
