Visible-Light-Induced Organocatalytic Borylation of Aryl Chlorides
Li Zhang, Lei Jiao*
*Center of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing 10084, China,
Email: Leijiao
mail.tsinghua.edu.cn
L. Zhang, L. Jiao, J. Am. Chem. Soc., 2019, 141, 9124-9128.
DOI: 10.1021/jacs.9b00917
Abstract
A diboron/methoxide/pyridine reaction system enables a photoactivation of an in situ generated super electron donor for an efficient, transition-metal-free borylation of unactivated aryl chlorides.
see article for more examples
formation of a mixture of super electron donors
Pyridine-Catalyzed Radical Borylation of Aryl Halides
L. Zhang, L. Jiao, J. Am. Chem. Soc., 2017, 139, 607-610.
Key Words
arylboronates, photochemistry, organocatalysis
ID: J48-Y2019
