Direct Intermolecular Anti-Markovnikov Hydroazidation of Unactivated Olefins
Hongze Li, Shou-Jie Shen, Cheng-Liang Zhu, Hao Xu*
*Department of Chemistry, Georgia State University, 100 Piedmont Avenue SE, Atlanta Georgia 30303, United States, Email: hxugsu.edu
H. Li, S.-J. Shen, C.-L. Zhu, H. Xu, J. Am. Chem. Soc., 2019, 141, 9415-9421.
DOI: 10.1021/jacs.9b04381 (free Supporting Information)
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A direct intermolecular anti-Markovnikov hydroazidation method for unactivated olefins is promoted by a catalytic amount of bench-stable benziodoxole at ambient temperature. This method facilitates previously difficult, direct addition of hydrazoic acid across a wide variety of unactivated olefins.
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