Electron Donor-Acceptor Complex Enabled Decarboxylative Sulfonylation of Cinnamic Acids under Visible-Light Irradiation
Qian-Qian Ge, Jia-Sheng Qian*, Jun Xuan*
*College of Chemistry & Chemical Engineering, Anhui University, Hefei, Anhui 230601, People’s Republic of China, Email: qianjshahu.edu.cn, xuanjunahu.edu.cn
Q.-Q. Ge, J.-S. Qian, J. Xuan, J. Org. Chem., 2019, 84, 8691-8701.
DOI: 10.1021/acs.joc.9b00552
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Abstract
Visible-light-induced decarboxylative sulfonylation of cinnamic acids with aryl sulfonate phenol esters offers a mild and green approach for the synthesis of vinyl sulfones with excellent functional group compatibility under photocatalyst and oxidant-free conditions.
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Key Words
vinylsulfones, photochemistry
ID: J42-Y2019