Organoselenium-Catalyzed Aza-Wacker Reactions: Efficient Access to Isoquinolinium Imides and an Isoquinoline N-Oxide
Huimin Li, Lihao Liao, Xiaodan Zhao*
*Institute of Organic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, P. R. China,
Email: zhaoxd3
mail.sysu.edu.cn
H. Li, L. Liao, X. Zhao, Synlett, 2019, 30, 1688-1692.
DOI: 10.1055/s-0039-1690103
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Abstract
An efficient organoselenium-catalyzed aza-Wacker reaction of olefinic hydrazones and oximes provides isoquinolinium imides and an isoquinoline N-oxides. This transformation involves a direct intramolecular C-H amination.
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Key Words
organoselenium catalysis, NFSI, aza-Wacker reaction, C-H amination, hydrazones, isoquinolines
ID: J72-Y2019
