Light-Mediated Dual Phosphine-/Copper-Catalyzed Atom Transfer Radical Addition Reaction
Oleg V. Fedorov, Sofya I. Scherbinina, Vitalij V. Levin, Alexander D. Dilman*
*N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, 119991 Moscow, Russian Federation,
Email: adil25
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O. V. Fedorov, S. I. Scherbinina, V. V. Levin, A. D. Dilman, J. Org. Chem., 2019, 84, 11068-11079.
DOI: 10.1021/acs.joc.9b01649
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Abstract
The combination of triphenylphosphine and copper(I) halide catalyzes an atom transfer radical addition reaction of activated organic halides to terminal alkenes under irradiation with 365 nm light using a light-emitting diode.
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Key Words
esters, bromides, photochemistry
ID: J42-Y2019
