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Nickel-Catalyzed Electrochemical Phosphorylation of Aryl Bromides

Ya Bai, Nian Liu, Shutao Wang, Siyu Wang, Shulin Ning, Lingling Shi, Lili Cui*, Zhuoqi Zhang, Jinbao Xiang*

*Jilin University, 1266 Fujin Road, Changchun, Jilin 130021; Changchun University of Science and Technology, 7989 Weixing Road, Changchun, Jilin 130022, P.R. China, Email: jbxiangjlu.edu.cn, cuilili1127gmail.com

Y. Bai, N. Liu, S. Wang, S. Wang, S. Ning, L. Shi, L. Cui, Z. Zhang, J. Xiang, Org. Lett., 2019, 21, 6795-6799.

DOI: 10.1021/acs.orglett.9b02475 (free Supporting Information)



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Abstract

A nickel-catalyzed electrochemical cross-coupling reaction of aryl bromides with dialkyl phosphites, ethyl phenylphosphinate, and diphenylphosphine oxide provides aryl phosphonates, aryl phosphinates, and arylphosphine oxides at room temperature using a simple undivided cell with inexpensive carbon electrodes.

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Key Words

phosphorylation, electrochemistry


ID: J54-Y2019