Free Radical Addition of Nitrile, Ketone, and Ester to Alkyne and the Selectivity Discussion
Yingxia Xiao and Zhong-Quan Liu*
*State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China, Email: liuzhqlzu.edu.cn
Y. Xiao, Z.-Q. Liu, Org. Lett., 2019, 21, 8810-8813.
DOI: 10.1021/acs.orglett.9b03444 (free Supporting Information)
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A convenient and general atom transfer radical addition (ATRA) of simple nitriles, ketones, and esters to alkynes provides a wide range of β,γ-unsaturated nitriles, ketones, and esters.
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