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Decarbonylative Phosphorylation of Carboxylic Acids via Redox-Neutral Palladium Catalysis

Chengwei Liu, Chong-Lei Ji, Tongliang Zhou, Xin Hong* and Michal Szostak*

*Department of Chemistry, Zhejiang University, Hangzhou 310027, China; Department of Chemistry, Rutgers University, Newark, New Jersey 07102, United States Email: hxchemzju.edu.cn, michal.szostakrutgers.edu

C. Liu, C.-L. Ji, T. Zhou, X. Hong, M. Szostak, Org. Lett., 2019, 21, 9256-9261.

DOI: 10.1021/acs.orglett.9b03678 (free Supporting Information)


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Abstract

A decarbonylative palladium catalysis enables the synthesis of organophosphorus compounds from ubiquitous aryl and vinyl carboxylic acids. The catalytic system olerates a wide range of functional groups.

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Key Words

phosphonates


ID: J54-Y2019