Nickel-Catalyzed Synthesis of Silanes from Silyl Ketones
Watchara Srimontree, Waranya Lakornwong and Magnus Rueping*
*Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany,
Email: magnus.rueping
rwth-aachen.de
W. Srimontree, W. Lakornwong, M. Rueping, Org. Lett., 2019, 21, 9330-9333.
DOI: 10.1021/acs.orglett.9b03487
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Abstract
An unprecedented nickel-catalyzed decarbonylative silylation of silyl ketones provides structurally diverse arylsilanes under mild reaction conditions.
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proposed mechanism
Key Words
ID: J54-Y2019
