Oxalic Acid Monothioester for Palladium-Catalyzed Decarboxylative Thiocarbonylation and Hydrothiocarbonylation
Bin Zhao, Yao Fu and Rui Shang*
*Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan, Email: ruichem.s.u-tokyo.ac.jp
B. Zhao, Y. Fu, R. Shang, Org. Lett., 2019, 21, 9521-9526.
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Oxalic acid monothioesters (OAM) can be used as a thioester synthetic equivalent for palladium-catalyzed decarboxylative thiocarbonylation of organohalides and hydrothiocarbonylation of unsaturated carbon-carbon bonds at room temperature with high chemo- and regioselectivity.
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