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Visible Light-Induced Borylation of C-O, C-N, and C-X Bonds

Shengfei Jin, Hang. T. Dang, Graham C. Haug, Ru He, Viet D. Nguyen, Vu T. Nguyen, Hadi D. Arman, Kirk S. Schanze and Oleg V. Larionov*

*Department of Chemistry, University of Texas at San Antonio, San Antonio, Texas 78249, United States, Email: oleg.larionovutsa.edu

S. Jin, H. T. Dang, G. C. Haug, R. He, V. D. Nguyen, V. T. Nguyen, H. D. Arman, K. S. Schanze, O. V. Larionov, J. Am. Chem. Soc., 2020, 142, 1603-1613.

DOI: 10.1021/jacs.9b12519 (free Supporting Information)



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Abstract

A general, metal-free visible light-induced photocatalytic borylation platform enables borylation of electron-rich derivatives of phenols and anilines, chloroarenes, as well as other haloarenes in the presence of phenothiazine as photocatalyst. The reaction exhibits excellent functional group tolerance.

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Key Words

borylation, photochemistry, organocatalysis


ID: J48-Y2020