Cobalt-Catalyzed Migrational Isomerization of Styrenes
Jiajin Zhao, Biao Cheng, Chenhui Chen and Zhan Lu*
*Department of Chemistry, Zhejiang University, Hangzhou 310058, China,
Email: luzhan
zju.edu.cn
J. Zhao, B. Cheng, C. Chen, Z. Lu, Org. Lett., 2020, 22, 837-841.
DOI: 10.1021/acs.orglett.9b04305
see article for more reactions
Abstract
An operationally simple, atom-economical, and efficient cobalt-catalyzed migrational isomerization of styrenes provides trisubstituted alkenes. Even with very low catalyst loadings, the reaction could be conducted in neat and completed in 1 h with excellent conversion and high E stereoselectivity.
see article for more examples
Key Words
ID: J54-Y2020
