Nickel-Catalyzed Hydroarylation of in Situ Generated 1,3-Dienes with Arylboronic Acids Using a Secondary Homoallyl Carbonate as a Surrogate for the 1,3-Diene and Hydride Source
Takashi Hamaguchi, Yoshiyuki Takahashi, Hiroaki Tsuji* and Motoi Kawatsura*
*Department of Chemistry, College of Humanities & Sciences, Nihon University, Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan,
Email: tsuji
chs.nihon-u.ac.jp, kawatsurchs.nihon-u.ac.jp
T. Hamaguchi, Y. Takahashi, H. Tsuji, M. Kawatura, Org. Lett., 2020, 22, 1124-1129.
DOI: 10.1021/acs.orglett.9b04634
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Abstract
A nickel-catalyzed hydroarylation of secondary homoallyl carbonates with arylboronic acids provides an efficient access to a broad range of hydroarylation products in high yields with high functional group compatibility without the use of an external hydride source.
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Key Words
ID: J54-Y2020
