Organic Chemistry Portal

Abstracts

Search:

Visible-Light-Promoted C2 Selective Arylation of Quinoline and Pyridine N-Oxides with Diaryliodonium Tetrafluoroborate

Dazhi Li, Ce Liang, Zaixing Jiang, Junzheng Zhang, Wang-Tao Zhuo, Fan-Yue Zou, Wan-Peng Wang, Guo-Lin Gao* and Jinzhu Song*

*School of Life Science and Technology, Harbin Institute of Technology, Harbin, Heilongjiang 150001, China, Email: gaoguolhit.edu.cn, songjinzhulabhit.edu.cn

D. Li, C. Liang, Z. Jiang, J. Zhang, W.-T. Zhuo, F.-Y. Zou, W.-P. Wang, G.-L. Gao, J. Song, J. Org. Chem., 2020, 85, 2733-2742.

DOI: 10.1021/acs.joc.9b02933 (free Supporting Information)



see article for more reactions

Abstract

Eosin Y catalyzes a visible-light-promoted C2 selective arylation of quinoline and pyridine N-oxides with diaryliodonium tetrafluoroborate as an arylation reagent under mild conditions. This methodology offers high regioselectivity, simple operation and good functional group tolerance.

see article for more examples



Key Words

quinolines, BQ, photochemistry, organocatalysis


ID: J42-Y2020