Homoleptic Bis(trimethylsilyl)amides of Yttrium Complexes Catalyzed Hydroboration Reduction of Amides to Amines
Pengqing Ye, Yinlin Shao*, Xuanzeng Ye, Fangjun Zhang*, Renhao Li, Jiani Sun, Beihang Xu and Jiuxi Chen*
*Wenzhou University, Wenzhou, 325035; Wenzhou Medical University, Wenzhou 325035, P.R. China, Email: shaoylwzu.edu.cn, rjzfjwmu.edu.cn, jiuxichenwzu.edu.cn
P. Ye, Y. Shao, X. Ye, F. Zhang, R. Li, J. Sun, B. Xu, J. Chen, Org. Lett., 2020, 22, 1265-1269.
see article for more reactions
Y[N(TMS)2]3 is an efficient homogeneous catalyst for the hydroboration of secondary amides and tertiary amides to provide the corresponding amines. The reaction tolerates various functional groups such as cyano, nitro, and vinyl groups.
see article for more examples