Magnesium-Catalyzed Stereoselective Hydrostannylation of Internal and Terminal Alkynes
Marc Magre, Marcin Szewczyk and Magnus Rueping*
*Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany,
Email: magnus.rueping
rwth-aachen.de
M. Magre, M. Szewcyk, M. Rueping, Org. Lett., 2020, 22, 1594-1598.
DOI: 10.1021/acs.orglett.0c00184
see article for more reactions
Abstract
A regio- and stereoselective magnesium-catalyzed hydrostannylation of internal and terminal alkynes provides the desired products with excellent yields and selectivities. A wide range of terminal and internal symmetrical and unsymmetrical alkynes can be converted using this alkaline earth metal catalyst as an effective alternative to transition metal catalysts.
see article for more examples
Key Words
ID: J54-Y2020
